57084-40-9Relevant articles and documents
Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes
Chen, Hua,Chen, Yi,Tang, Xiaoxiao,Liu, Shunfa,Wang, Runping,Hu, Tianbao,Gao, Lu,Song, Zhenlei
, p. 4695 - 4699 (2019)
A Rh-catalyzed reaction of silacyclobutanes (SCBs) with unactivated alkynes has been developed to form silacyclohexenes with high chemoselectivity. Good enantioselectivity at the stereogenic silicon center was achieved using a chiral phosphoramidite ligand. The resulting silacyclohexenes are useful scaffolds for synthesizing structurally attractive silacyclic compounds.