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2351-34-0

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Product FOB Price Min.Order Supply Ability Supplier
1-CHLORO-1-METHYLSILETANE
Cas No: 2351-34-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
2351-34-0 1-CHLORO-1-METHYLSILACYCLOBUTANE
Cas No: 2351-34-0
USD $ 8900.0-8900.0 / Gram 1 Gram 200 Gram/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Top Purity CAS 2351-34-0 with fast shipping
Cas No: 2351-34-0
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
1-CHLORO-1-METHYLSILACYCLOBUTANE
Cas No: 2351-34-0
No Data 10 Kilogram 1 Kilogram/Day HANGZHOU CLAP TECHNOLOGY CO,.LTD Contact Supplier
1-CHLORO-1-METHYLSILETANE CAS NO.2351-34-0
Cas No: 2351-34-0
No Data No Data No Data Jilin haofei import and export trade Co.,Ltd Contact Supplier
CYCLOTRIMETHYLENEMETHYLCHLOROSILANE
Cas No: 2351-34-0
No Data 1 Gram 2000 Metric Ton/Year Hunan chemfish Pharmaceutical co.,Ltd Contact Supplier
1-Chloro-1-Methylsilacyclobutane
Cas No: 2351-34-0
No Data No Data No Data GIHI CHEMICALS CO.,LIMITED Contact Supplier
Cyclotrimethylenemethylchlorosilane
Cas No: 2351-34-0
No Data No Data No Data Kono Chem Co.,Ltd Contact Supplier
1-Chloro-1-methylsiletane
Cas No: 2351-34-0
No Data No Data No Data Finetech Industry Limited Contact Supplier
1-Chloro-1-Methylsilacyclobutane
Cas No: 2351-34-0
No Data No Data 1 Kilogram/Week Shanghai Chemlab New Materials Co., Ltd. Contact Supplier

2351-34-0 Usage

Physical properties

bp 103°C; d 0.985 g cm?3.

Uses

Siletanes (silacyclobutanes) represent a unique class of silicon-based reagents that have enjoyed much success in a number of synthetic applications including aldol reactions, allylations, cross-coupling reactions, carbosilane oxidations, and ring expansions. The manifestation of their strain in enhanced Lewis acidity and in the ring opening to silanols accounts for their utility. 1-Chloro-1-methylsiletane can be used for the preparation of the various siletane derivatives for these applications.Grignard reagents react efficiently with 1-chloro-1-methylsiletane to provide the corresponding aryl-, alkenyl-, or alkylsiletanes (eqs 1–3).On the contrary, reactions with alkyllithiums are limited to the reaction of 1 with a lithium acetylide (eq 4).The reaction of 1 with an intermediate vinylalane obtained by hydroalumination of 1-heptyne gave (E)-1-heptenylmethylsiletane in >99/1 isomeric purity (eq 5).The reaction of 1 with LiAlD4 afforded 1-deuterio-1-methylsiletane (eq 6).

Uses

Intermediate in the formation of enoxysilacyclobutanes.

Preparation

siletane can be prepared in large quantities byWurtz coupling reaction of dichloro-3-chloropropylmethylsilane with Mg.It is commercially available from Gelest and Aldrich chemical company.
InChI:InChI=1/C4H9ClSi/c1-6(5)3-2-4-6/h2-4H2,1H3

2351-34-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (411582)  1-Chloro-1-methylsilacyclobutane  98% 2351-34-0 411582-5G 2,453.49CNY Detail

2351-34-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-chloro-1-methylsiletane

1.2 Other means of identification

Product number -
Other names 1-chloro-1-methyl-1-silacyclobutane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2351-34-0 SDS

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