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A stereodivergent approach to chiral nonracemic N-protected α,α-dialkylated amino acids
Spino, Claude,Gobdout, Cedrickx
, p. 12106 - 12107 (2007/10/03)
Menthyl carboxaldehyde is used as a chiral auxiliary to make quaternary amino acids of either configuration via a stereodivergent approach that includes an SN2′ displacement by a cuprate reagent and a Curtius rearrangement as key steps. Copyright