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62214-78-2

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62214-78-2 Usage

General Description

1-Benzyl-3-hydroxypyridinium bromide is a chemical compound with the molecular formula C12H14BrNO. It is an organic compound that contains a quaternary ammonium cation and is commonly used as a phase transfer catalyst in organic synthesis. 1-BENZYL-3-HYDROXYPYRIDINIUM BROMIDE is a soluble crystalline white powder that is commonly used to facilitate the transfer of ions between immiscible phases, allowing for the extraction of organic compounds from water or other solvents. It is also used as a catalyst in reactions such as alkylations and oxidations. Additionally, 1-Benzyl-3-hydroxypyridinium bromide has been studied for its potential antimicrobial properties and has shown promising results in inhibiting the growth of certain bacteria and fungi.

Check Digit Verification of cas no

The CAS Registry Mumber 62214-78-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,2,1 and 4 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 62214-78:
(7*6)+(6*2)+(5*2)+(4*1)+(3*4)+(2*7)+(1*8)=102
102 % 10 = 2
So 62214-78-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H11NO.BrH/c14-12-7-4-8-13(10-12)9-11-5-2-1-3-6-11;/h1-8,10H,9H2;1H

62214-78-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-benzyl-3-hydroxypyridinium bromide

1.2 Other means of identification

Product number -
Other names 1-benzyl-3-hydroxy-pyridinium

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:62214-78-2 SDS

62214-78-2Relevant articles and documents

Synthesis and evaluation of the performance of a small molecule library based on diverse tropane-related scaffolds

Lowe, Robert A.,Taylor, Dale,Chibale, Kelly,Nelson, Adam,Marsden, Stephen P.

supporting information, (2020/03/25)

A unified synthetic approach was developed that enabled the synthesis of diverse tropane-related scaffolds. The key intermediates that were exploited were cycloadducts formed by reaction between 3-hydroxy-pyridinium salts and vinyl sulfones or sulfonamides. The diverse tropane-related scaffolds were formed by addition of substituents to, cyclisation reactions of, and fusion of additional ring(s) to the key bicyclic intermediates. A set of 53 screening compounds was designed, synthesised and evaluated in order to determine the biological relevance of the scaffolds accessible using the synthetic approach. Two inhibitors of Hedgehog signalling, and four compounds with weak activity against the parasite P. falciparum, were discovered. Three of the active compounds may be considered to be indotropane or pyrrotropane pseudo natural products in which a tropane is fused with a fragment from another natural product class. It was concluded that the unified synthetic approach had yielded diverse scaffolds suitable for the design of performance-diverse screening libraries.

TRICYCLIC COMPOUNDS AND THEIR USE IN THE TREATMENT OF CANCER

-

Page/Page column 44, (2017/03/21)

There is provided compounds of formula (I), or pharmaceutically-acceptable salts thereof, wherein X, Y, Z, R1 and R2 have meanings provided in the description, which compounds are useful in the treatment of cancers.

Efficient and chemoselective reduction of pyridines to tetrahydropyridines and piperidines via rhodium-catalyzed transfer hydrogenation

Wu, Jianjun,Tang, Weijun,Pettman, Alan,Xiao, Jianliang

supporting information, p. 35 - 40 (2013/03/13)

Promoted by iodide anion the rhodium complex dimer, [Cp RhCl 2]2, catalyzes efficiently the transfer hydrogenation of various quaternary pyridinium salts under mild conditions, affording not only piperidines but also 1,2,3,6-tetrahydropyridines in a highly chemoselective fashion, depending on the substitution pattern at the pyridinium ring. The reduction is conducted in azeotropic formic acid/triethylamine (HCOOH-Et 3N) mixture at 40 °C, with catalyst loadings as low as 0.005mol% being feasible. Copyright

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