626-37-9Relevant articles and documents
Nitrimines: VII. Reaction of S,S′-Dimethyl-N-nitroimidodithiocarbonate with Alkali. Synthesis of S-Methyl-N-nitrothiocarbamate and Its Salts
Astakhov,Antishin,Nefedov,Salnikov,Buka
, p. 1638 - 1642 (2018)
Reaction of S,S′-dimethyl-N-nitroimidodithiocarbonate with alkali in aqueous-alcoholic solution results in salts of S-methyl-N-nitrothiocarbamate. In anhydrous ethanol a salt of nitrouretane is obtained. By the reaction of S-methyl-N-nitrothiocarbamate salts with hydrazine 4-nitrosemicarbazide salts were prepared.
Dinitramide and its salts 10. * synthesis of dinitramide salts from N,N-dinitro derivatives of organic amides
Luk'yanov,Kozlova,Shitov,Konnova,Kalinina,Tartakovsky
, p. 863 - 867 (1996)
N,N-Dinitro derivatives of alkylurethanes, benzamide, and p-toluenesulfamide were synthesized for the first time. Their reactions with ammonia afforded the ammonium salt of dinitramide in 44-85 % yields.
Activation of nitrogen bronsted acids: Synthesis and reactivity of a new class of nitrogen acid complexes
Bohle, D. Scott,Chua, Zhijie
, p. 11160 - 11172 (2014)
The nitrogen acids RC(O)NHNO2, N-nitroamide, R = CH3 (1), C2H5 (2) and N-nitrocarbamate, R′OC(O)NHNO2, R′ = CH3 (3), C2H5 (4) are a class of primary N-nitrocarboxamide compounds that oxidatively add to trans-Ir(I)(Cl)(N2)(PPh3)2 to give six-coordinate Ir(III)(η2-(NO2)-nitrogen acid)(H)(Cl)(PPh3)2 complexes 5-8. Unexpected fluxional behavior of the complexes in solution is observed by 1H NMR spectroscopy. Reaction intermediates of the oxidative addition reactions were also observed and monitored using 31P and 1H NMR and solution IR spectroscopies. Complex 5 reacts with methyl triflate in CH3CN to generate bis(acetonitrile) complex (9) from a net loss of the nitrogen acid anion. P(CH3)2Ph reacts with 5 to give phosphine-substituted and P(CH3)2Ph addition isomers (10). Reactivity studies of 5 with CO gave metastable CO adduct isomer 11, which loses CO on prolonged standing in solution. (Chemical Equation Presented).
