63399-86-0

Basic information

• Product Name: Benzene, (4-methyl-1,2-hexadienyl)-
• CAS NO: 63399-86-0
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 63399-86-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, (4-methyl-1,2-hexadienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-methyl-1,2-hexadienyl)-(63399-86-0)
• EPA Substance Registry System: Benzene, (4-methyl-1,2-hexadienyl)-(63399-86-0)

Safety Data

• Hazardous Substances Data: 63399-86-0(Hazardous Substances Data)

Upstream product

• 926-62-5 isobutylmagnesium bromide 
• 122044-10-4 Methanesulfinic acid (R)-1-phenyl-prop-2-ynyl ester 
• 1113-78-6 tri(sec-butyl)borane 
• 16169-88-3 1-phenylprop-2-ynyl acetate 

Relevant articles and documents

Highly Stereoselective Synthesis of Chiral Alkylallenes by Organocopper(I)-Induced Anti 1,3-Substitution of Chiral Propynyl Esters

The synthesis of chiral 1,3-dialkylallenes R1CH=C=CHR2 of high enantiomeric purity, by applying homogeneous reaction between organocopper(I) reagents of type 2CuX>MgX-LiX> and chiral propynyl methanesulfonates or sulfinates at low temperatures in THF, is reported.The reactions are generally fast; typically complete conversion is obtained within a few minutes at -60 deg C.Overall, high anti stereoselectivity is observed.A plausible mechanism is put forward, and comparison is made with the stereochemistry of reactions of comparable substrates with d10 complexes, e.g. of Pd(0).