69420-67-3

Basic information

• Product Name: (+/-)-trans-[2-(pyrrolidinyl)]cyclohexanol
• Synonyms: (+/-)-trans-[2-(pyrrolidinyl)]cyclohexanol
• CAS NO: 69420-67-3
• Molecular Weight: 169.267
• Mol File: 69420-67-3.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: (+/-)-trans-[2-(pyrrolidinyl)]cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-trans-[2-(pyrrolidinyl)]cyclohexanol(69420-67-3)
• EPA Substance Registry System: (+/-)-trans-[2-(pyrrolidinyl)]cyclohexanol(69420-67-3)

Safety Data

• Hazardous Substances Data: 69420-67-3(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 286-20-4 cyclohexene oxide 
• 286-20-4 cyclohexane-1,2-epoxide 

Downstream Products

• 247024-86-8 (1R,2R)-trans-2-(pyrrolidin-1'-yl)-cyclohehanol 
• 174293-29-9 trans-2-(1-pyrrolidinyl)cyclohexanol 
• 118207-34-4 2-(pyrrolidin-1-yl)cyclohexanone 
• 146664-13-3 (3-Methoxy-phenyl)-carbamic acid (1S,2S)-2-pyrrolidin-1-yl-cyclohexyl ester; hydrochloride 
• 130993-58-7 Methanesulfonic acid (1R,2R)-2-pyrrolidin-1-yl-cyclohexyl ester 
• 26613-36-5 (4-Pentyloxy-phenyl)-carbamic acid (1S,2S)-2-pyrrolidin-1-yl-cyclohexyl ester; hydrochloride 
• 101590-75-4 4-amino-benzoic acid-(trans-2-pyrrolidino-cyclohexyl ester) 

Relevant articles and documents

Quaternary ammoniums and a cationic sodium complex as supramolecular catalysts in ring-opening of epoxides by amines

Supramolecular ionic organocatalysts and a metal-based catalyst were investigated in the ring-opening of epoxides by amines, without any artifice to enhance conversion (i.e., solvophobic effect, extended reaction time, heating, excess of amine, high catalyst loading). Different β-amino-alcohols were obtained in satisfying conversion (50-80%) in 24 h, under mild conditions.

M-Type SrFe12O19Ferrite: An Efficient Catalyst for the Synthesis of Amino Alcohols under Solvent-Free Conditions

Magnetically separable strontium hexaferrite SrFe12O19 was prepared using the chemical coprecipitation method, and the nanostructured material was characterized by X-ray diffraction, scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), and BET analysis. The SEM images showed the homogeneity of the chemical composition of SrFe12O19 and uniform distribution of size and morphology. The pore size of the nanomaterial and its specific area were determined by BET measurements. Strontium hexaferrite SrFe12O19 exhibited a strong magnetic field, which is highly suitable in the heterogeneous catalysis as it can be efficiently separated from the reaction. The magnetic nanocatalyst showed high activity and environmentally benign heterogeneous catalysts for the epoxide ring-opening with amines affording β-amino alcohols under solvent-free conditions. When unsymmetrical epoxides were treated in the presence of aromatics amines, the regioselectivity was influenced by the electronic and steric factors. Total regioselectivity was observed for the reactions performed with aliphatic amines. The magnetically SrFe12O19 nanocatalyst showed excellent recyclability with continuously good catalytic activities after four cycles.

Three-dimensional {Co3+-Zn2+} and {Co 3+-Cd2+} networks originated from carboxylate-rich building blocks: Syntheses, structures, and heterogeneous catalysis

The present work shows the utilization of Co3+ complexes appended with either para- or meta-arylcarboxylic acid groups as the molecular building blocks for the construction of three-dimensional {Co 3+-Zn2+} and {Co3+-Cd2+} heterobimetallic networks. The structural characterizations of these networks show several interesting features including well-defined pores and channels. These networks function as heterogeneous and reusable catalysts for the regio- and stereoselective ring-opening reactions of various epoxides and size-selective cyanation reactions of assorted aldehydes.