713542-04-2

Basic information

• Product Name: Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-
• Synonyms: 1,3,5-tri(anthracen-9-yl)benzene;Anthracene,9,9',9''-(1,3,5-benzenetriyl)tris
• CAS NO: 713542-04-2
• Molecular Formula: C48H30
• Molecular Weight: 606.766
• Mol File: 713542-04-2.mol
• Article Data: 4

Chemical Properties

• Melting Point: >300°C
• CAS DataBase Reference: Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-(CAS DataBase Reference)
• NIST Chemistry Reference: Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-(713542-04-2)
• EPA Substance Registry System: Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-(713542-04-2)

Safety Data

• Hazardous Substances Data: 713542-04-2(Hazardous Substances Data)

Usage

Description

Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-, also known as 1,3,5-Tri(anthracen-9-yl)benzene, is a polycyclic aromatic hydrocarbon characterized by its unique molecular structure consisting of three anthracene units connected by a central benzene core. Anthracene, 9,9',9''-(1,3,5-benzenetriyl)trisexhibits distinct chemical and physical properties, making it suitable for various applications in different industries.

Uses

Used in Energy Storage Applications:
Anthracene, 9,9',9''-(1,3,5-benzenetriyl)trisis used as a precursor in the preparation of porous metal-organic polyhedral frameworks. These frameworks are employed in methane storage due to their high surface area, porosity, and stability, offering an efficient solution for natural gas storage and transportation.
Used in Electronics Industry:
In the electronics industry, Anthracene, 9,9',9''-(1,3,5-benzenetriyl)trisis utilized in the preparation of starburst oligofluorenes, which serve as deep-blue OLED (Organic Light Emitting Diode) emitters. These emitters are crucial for the development of high-performance displays and lighting systems, providing vibrant colors, high contrast, and energy efficiency.

Upstream product

• 642-31-9 9-anthracene aldehyde 
• 58349-77-2 9-(ω-nitrovinyl)anthracene 
• 583-53-9 2,3-dibromobenzene 
• 123335-02-4 bis-(2-bromophenyl)methanol 
• 2672-58-4 1,3,5-tris-(methoxycarbonyl)benzene 
• 61592-89-0 2,2’-dibromodiphenylmethane 
• 626-39-1 1,3,5-trisbromobenzene 
• 100622-34-2 anthracene-9-boronic acid 

Relevant articles and documents

Porous Metal-Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage

Natural gas (methane, CH4) is widely considered as a promising energy carrier for mobile applications. Maximizing the storage capacity is the primary goal for the design of future storage media. Here we report the CH4 storage properties in a family of isostructural (3,24)-connected porous materials, MFM-112a, MFM-115a, and MFM-132a, with different linker backbone functionalization. Both MFM-112a and MFM-115a show excellent CH4 uptakes of 236 and 256 cm3 (STP) cm-3 (v/v) at 80 bar and room temperature, respectively. Significantly, MFM-115a displays an exceptionally high deliverable CH4 capacity of 208 v/v between 5 and 80 bar at room temperature, making it among the best performing metal-organic frameworks for CH4 storage. We also synthesized the partially deuterated versions of the above materials and applied solid-state 2H NMR spectroscopy to show that these three frameworks contain molecular rotors that exhibit motion in fast, medium, and slow regimes, respectively. In situ neutron powder diffraction studies on the binding sites for CD4 within MFM-132a and MFM-115a reveal that the primary binding site is located within the small pocket enclosed by the [(Cu2)3(isophthalate)3] window and three anthracene/phenyl panels. The open Cu(II) sites are the secondary/tertiary adsorption sites in these structures. Thus, we obtained direct experimental evidence showing that a tight cavity can generate a stronger binding affinity to gas molecules than open metal sites. Solid-state 2H NMR spectroscopy and neutron diffraction studies reveal that it is the combination of optimal molecular dynamics, pore geometry and size, and favorable binding sites that leads to the exceptional and different methane uptakes in these materials.

Direct Transformation of Esters into Arenes with 1,5-Bifunctional Organomagnesium Reagents

A direct transformation of carboxylic acid esters into arenes with 1,5-bifunctional organomagnesium reagents is described. This efficient and practical method enables the one-step defunctionalization of various carboxylic acid esters to prepare benzene, anthracene, tetracene, and pentacene derivatives. A double nucleophilic addition of the 1,5-organodimagnesium reagent to the ester is followed by an immediate 1,4-elimination reaction that leads to the direct [5+1] formation of a new aromatic ring.