72049-76-4Relevant articles and documents
ELECTROGENERATED ACID AS A POWERFUL CATALYST FOR TRANSFORMATION OF EPOXIDES TO KETONES AND ACETONIDES
Uneyama, Kenji,Isimura, Akihiro,Fujii, Kazuyuki,Torii, Sigeru
, p. 2857 - 2860 (2007/10/02)
Electrochemical Transformation of epoxides 1 to ketones 2 and acetonides 3 were achieved by using an electrogenerated acid-catalyst.A combination of M(ClO4)n with polar aprotic solvents is useful for the electrochemical transformation.
Stereoselective Synthesis of (+/-)-Irones
Torii, Sigeru,Uneyama, Kenji,Matsunami, Setsuo
, p. 16 - 20 (2007/10/02)
β-, α-cis-, and α-trans-irones (1, 2a, and 2b) have been prepared via 2,5,6,6-tetramethyl-1-cyclohexene (7) and 1,4β,5,5-tetramethyl-6β-cyclohexene (8a) and its C-6 epimer (8b).Electrochemical epoxidation of