762242-53-5

Basic information

• Product Name: 1-phenylvinyl N,N-dimethylcarbamate
• Synonyms: 1-phenylvinyl N,N-dimethylcarbamate
• CAS NO: 762242-53-5
• Molecular Weight: 191.23
• Mol File: 762242-53-5.mol

Chemical Properties

• CAS DataBase Reference: 1-phenylvinyl N,N-dimethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylvinyl N,N-dimethylcarbamate(762242-53-5)
• EPA Substance Registry System: 1-phenylvinyl N,N-dimethylcarbamate(762242-53-5)

Safety Data

• Hazardous Substances Data: 762242-53-5(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 79-44-7 N,N-Dimethylcarbamoyl chloride 

Downstream Products

• 1573114-50-7 (1Z,3E)-4-(3-nitrophenyl)-1-phenylbuta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-49-4 (1Z,3E)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-48-3 (1Z,3E)-4-(2-chlorophenyl)-1-phenylbuta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-47-2 (1Z,3E)-1-phenyl-4-(4-(trifluoromethyl)phenyl)buta-1,3-dien-1-yldimethylcarbamate 
• 1573114-46-1 (1Z,3E)-1,4-diphenylbuta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-45-0 (1Z,3E)-4-(methylsulfonyl)-1-phenylbuta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-44-9 (1Z,3E)-5-oxo-1-phenylhepta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-86-9 (1Z,3E)-5-oxo-1-phenylhepta-1,3-dien-1-yl dimethylcarbamate 
• 1573114-43-8 (1Z,3E)-5-oxo-1-phenylhexa-1,3-dien-1-yl dimethylcarbamate 

Relevant articles and documents

Using Rh(III)-catalyzed C-H activation as a tool for the selective functionalization of ketone-containing molecules

Due to the strong potential of C-H activation in many areas of organic chemistry, the use of a pre-existing carbonyl group for the installation of a directing group to enable selective and predictable α-alkenylation with activated olefins as coupling partners is described. This Heck-type reaction would then lead either to β,γ-unsaturated ketones or to variously substituted 1,4-butadienes depending on the conditions used for the cleavage of the directing group.

Rh(III)-catalyzed C-H activation with allenes to synthesize conjugated olefins

RhIII-catalyzed C-H activation with allenes produces highly unsaturated conjugated olefins. The reaction is applicable to both olefin and arene C(sp2)-H and is compatible with a variety of functional groups. The products can be further transformed into ot

Nickel-catalyzed efficient and practical Suzuki-Miyaura coupling of alkenyl and aryl carbamates with aryl boroxines

(Figure Presented) Suzuki-Miyaura coupling of unactivated alkenyl carbamates Is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.

Enantioselective rhodium-catalyzed hydrogenation of enol carbamates in the presence of monodentate phosphines

The rhodium-catalyzed asymmetric hydrogenation of different acyclic and cyclic enol carbamates to give optically active carbamates has been examined in the presence of chiral monodentate ligands based on a 4,5-dihydro-3H-dinaphthophosphepine motif 4. The

Enantioselective Rh-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites

(Chemical Equation Presented) Monodentate phosphoramidites, in particular PipPhos and its octahydro analogue, are excellent ligands for the rhodium-catalyzed asymmetric hydrogenation of aromatic enol acetates, enol carbamates, and 2-dienol carbamates up to 98% ee. These latter substrates were hydrogenated selectively to the carbamates of the allyl alcohol.

The application of monodentate secondary phosphine oxide ligands in rhodium- and iridium-catalyzed asymmetric hydrogenation

Enantiopure secondary phosphine oxides have been tested as ligands in the rhodium- and iridium-catalyzed asymmetric hydrogenation of functionalized olefins. tert-Butylphosphinoyl benzene turned out to be a versatile ligand in the iridium-catalyzed hydroge