78823-36-6

Basic information

• Product Name: p-nitrobenzoic-propionic anhydride
• Synonyms: p-nitrobenzoic-propionic anhydride
• CAS NO: 78823-36-6
• Molecular Weight: 223.185
• Mol File: 78823-36-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-nitrobenzoic-propionic anhydride(CAS DataBase Reference)
• NIST Chemistry Reference: p-nitrobenzoic-propionic anhydride(78823-36-6)
• EPA Substance Registry System: p-nitrobenzoic-propionic anhydride(78823-36-6)

Safety Data

• Hazardous Substances Data: 78823-36-6(Hazardous Substances Data)

Upstream product

• 79-03-8 propionyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 82251-68-1 p-nitrobenzic benzenesulphonic mixed anhydride 
• 802294-64-0 propionic acid 
• 201230-82-2 carbon monoxide 
• 137-40-6 sodium proprionate 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 

Downstream Products

• 57794-08-8 (1S,2S)-trans-1,2-Cyclohexanediol 
• 1072-86-2 (1R,2R)-trans-1,2-cyclohexanediol 
• 1227311-62-7 cyclohexane-1,2-diol 
• 7402-18-8 cyclohexane-1,2-diol 
• 108268-28-6 (1R,2R)-cycloheptane-1,2-diol 
• 13553-19-0 (1S,2S)-cycloheptane-1,2-diol 
• 1532564-69-4 C₁₀H₁₈O₃ 
• 4277-32-1 (1S,2S)-cyclooctane-1,2-diol 
• 1532564-70-7 C₁₁H₂₀O₃ 
• 930-46-1 (1R,2R)-cyclopentane-1,2-diol 
• 63261-45-0 (S,S)-cyclopentane-1,2-diol 
• 1532564-68-3 C₈H₁₄O₃ 

Relevant articles and documents

En route to multicatalysis: Kinetic resolution of trans-cycloalkane-1,2- diols via oxidative esterification

We demonstrate the application of a multicatalyst to the oxidation of a broad variety of aldehydes and subsequent enantioselective esterification of the incipient acids with (±)-trans-cycloalkane-1,2-diols. This reaction operates well with a multicatalyst bearing two independent catalytic moieties that provide monoprotected 1,2-diols in one pot.

Reaction of Diazonium Salts with Transition Metals. 6. Preparation of Mixed Acid Anhydrides from Arenediazonium Salts and Sodium Carboxylates under Palladium(0) Catalysis

The palladium(0)-catalyzed reaction of arenediazonium tetrafluoroborates with carbon monoxide and sodium carboxylates in acetonitrile at 25 deg C gave mixed acid anhydrides, ArCOOCOR (Ar = 3-Me-Ph, 4-Me-Ph, 2-MeO-Ph, 4-Br-Ph, 4-I-Ph, 3-NO2-Ph, 4-NO2-Ph, and Ph; R = H, Me, Et, t-Bu, and Ph) in good yields.Homoaromatic acid anhydrides, (ArCO)2O, were obtained by heating of ArCOOCOMe at 100-120 deg C under vacuum.ArCOOCO-t-Bu can be utilized to obtain the corresponding arenecarboxamides by the reaction with some amines.