83720-10-9Relevant articles and documents
An Enantioselective Total Synthesis of (-)-Talaromycins A and B
Smith, Amos B.,Thompson, Andrew S.
, p. 1469 - 1471 (1984)
The first enantioselective total synthesis of (-)-talaromycin A and B from a common advanced intermediate is described.
Enantioselective Total Synthesis of the Mycotoxin (-)-Talaromycin B by a Hetero Diels-Alder Reaction
Tietze, Lutz F.,Schneider, Christoph
, p. 2476 - 2481 (2007/10/02)
(-)-Talaromycin B was formed in an overall yield of 5 percent in nine steps via a hetero Diels-Alder reaction of the exocyclic vinyl ether 3 and methyl O-benzoyldiformylacetate (4) as the key transformation.The enantiomerically pure vinyl ether 3 was prep
An enantiospecific synthesis of (-)-talaromycins A and B from D-fructose
Cubero, Isidoro Izquierdo,Lopez-Espinosa, Maria T. Plaza
, p. 293 - 304 (2007/10/02)
(3R,4R,5S,6R,9RS)-9-Ethyl-3,4,5-trihydroxy-1,7-dioxaspiroundecane (9) has been synthesised from 2,3;4,5-di-O-isopropylidene-β-D-fructopyranose (3) and transformed into (-)-talaromycin A (1). (-)-Talaromycin B (2) was obtained by isomerisation of 1 in acid medium.