91703-99-0Relevant academic research and scientific papers
SPIROKETALS: A TOTAL SYNTHESIS OF (+/-)-TALAROMYCIN B VIA A STEREOSELECTIVE CATION-OLEFIN CYCLISATION STEP
Kay, I.Trevor,Bartholomew, David
, p. 2035 - 2038 (1984)
The acid catalysed rearrangement of an acetal derived from 2-hydroxymethyl-3-butene-1-ol proceeding via an intramolecular cation-olefin cyclisation provides acces to a 4-hydroxytetrahydropyran and thence to (+/-)-talaromycin B.
