854497-57-7

Basic information

• Product Name: 2-Methyl-propane-2-sulfinic acid [3-phenyl-prop-(E)-ylidene]-amide
• Synonyms: 2-Methyl-propane-2-sulfinic acid [3-phenyl-prop-(E)-ylidene]-amide
• CAS NO: 854497-57-7
• Molecular Weight: 237.366
• Mol File: 854497-57-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Methyl-propane-2-sulfinic acid [3-phenyl-prop-(E)-ylidene]-amide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methyl-propane-2-sulfinic acid [3-phenyl-prop-(E)-ylidene]-amide(854497-57-7)
• EPA Substance Registry System: 2-Methyl-propane-2-sulfinic acid [3-phenyl-prop-(E)-ylidene]-amide(854497-57-7)

Safety Data

• Hazardous Substances Data: 854497-57-7(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 343338-28-3 (S)-2-methylpropane-2-sulfinamide 

Downstream Products

• 380848-24-8 N-(1-phenethyl-allyl)-3-phenyl-propionamide 
• 380848-36-2 N-(1-oxiranyl-3-phenyl-propyl)-3-phenyl-propionamide 
• 380848-37-3 N-(1-oxiranyl-3-phenyl-propyl)-butyramide 
• 380848-27-1 N-(1-phenethyl-allyl)-butyramide 
• 380848-17-9 (S)-5-phenylpent-1-en-3-amine 

Relevant articles and documents

Stereoselective synthesis of enantioenriched acetylenic 1,2-amino alcohols

The stereoselective synthesis of enantioenriched anti-and syn-4-aminoalk-1-yn-3-ols is described. Initial reaction of racemic 3-(methoxymethoxy)allenylzinc with enantiopure Ellman's (SS)-(tert- butylsulfinyl)imines was shown to give straightfor

KHSO4-mediated condensation reactions of tert-butanesulfinamide with aldehydes. Preparation of tert-butanesulfinyl aldimines

Optically pure tert-butanesulfinyl aldimines 1 were prepared by direct condensation of chiral tert-butanesulfinamide 3 with aldehydes 2 in high yields in the presence of KHSO4. The main advantage of KHSO4 is that it is applicable to the condensation reactions of a variety of aldehydes, including electron deficient and electron rich (hetereo)aromatic aldehydes, as well as aliphatic aldehydes.