92853-85-5

Basic information

• Product Name: 2-chloro-4-phenyl-6-(p-tolyl)-1,3,5-triazine
• Synonyms: 2-chloro-4-phenyl-6-(p-tolyl)-1,3,5-triazine
• CAS NO: 92853-85-5
• Molecular Weight: 281.744
• Mol File: 92853-85-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-4-phenyl-6-(p-tolyl)-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-4-phenyl-6-(p-tolyl)-1,3,5-triazine(92853-85-5)
• EPA Substance Registry System: 2-chloro-4-phenyl-6-(p-tolyl)-1,3,5-triazine(92853-85-5)

Safety Data

• Hazardous Substances Data: 92853-85-5(Hazardous Substances Data)

Upstream product

• 98-80-6 phenylboronic acid 
• 1700-02-3 2,4-dichloro-6-phenyl-1,3,5-triazine 
• 5720-05-8 4-methylphenylboronic acid 
• 2622-89-1 diphenylborinic acid 
• 66117-64-4 di(p-tolyl)borinic acid 

Relevant articles and documents

A Sequential Suzuki Coupling Approach to Unsymmetrical Aryl s-Triazines from Cyanuric Chloride

A practical approach has been developed for efficient synthesis of unsymmetrical aryl s-triazines via highly selective sequential Suzuki coupling of cyanuric chloride (2,4,6-trichlorotriazine) with aryl or vinyl boronic or diarylborinic acids catalysed by 0.1–0.5 mol% Pd(PPh3)2Cl2 under mild conditions. The second and third Suzuki couplings for unsymmetrically trisubstituted aryl s-triazines could be more practically conducted in one-pot procedure. An electron-withdrawing conjugate group at phenyl ring of arylboronic acids was unexpectedly found to completely block the coupling while steric hindrance from an ortho electron-donating substituent could be overcome. (Figure presented.).