92862-23-2

Basic information

• Product Name: pentadecan-5-one
• Synonyms: 5-Pentadecanone
• CAS NO: 92862-23-2
• Molecular Formula: C₁₅H₃₀O
• Molecular Weight: 226.3981
• Mol File: 92862-23-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 292.6°C at 760 mmHg
• Flash Point: 83.1°C
• Density: 0.828g/cm³
• Vapor Pressure: 0.00182mmHg at 25°C
• Refractive Index: 1.436
• CAS DataBase Reference: pentadecan-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: pentadecan-5-one(92862-23-2)
• EPA Substance Registry System: pentadecan-5-one(92862-23-2)

Safety Data

• Hazardous Substances Data: 92862-23-2(Hazardous Substances Data)

Upstream product

• 110-62-3 pentanal 
• 872-05-9 1-Decene 
• 109-72-8 n-butyllithium 
• 627-90-7 ethyl undecanoate 
• 17746-05-3 undecanoyl chloride 
• 107399-10-0 undecanoyltrimethylsilane 
• 612069-79-1 pentadec-14-en-5-ol 
• 142981-63-3 5-methoxy-5-(trimethylsilyl)pentadecane 
• 142981-62-2 5-hydroxy-5-(trimethylsilyl)pentadecane 
• 17049-50-2 n-decyl magnesium bromide 
• 3431-67-2 di-n-butylcadmium 
• 542-69-8 1-iodo-butane 

Downstream Products

• 629-62-9 pentadecane 

Relevant articles and documents

A General Approach to Intermolecular Olefin Hydroacylation through Light-Induced HAT Initiation: An Efficient Synthesis of Long-Chain Aliphatic Ketones and Functionalized Fatty Acids

Herein, an operationally simple, environmentally benign and effective method for intermolecular radical hydroacylation of unactivated substrates by employing photo-induced hydrogen atom transfer (HAT) initiation is described. The use of commercially available and inexpensive photoinitiators (Ph2CO and NHPI) makes the process attractive. The olefin hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.

An effective one-pot conversion of acid chlorides to aldehydes and ketones

Aldehydes and ketones were synthesized from their respective acid chlorides via a one-pot protocol. Morpholine amide intermediates that were readily prepared by the aminolysis of various acid chlorides with diisobutyl(morpholino) aluminum smoothly reacted with the reducing agent LDBMA and the organolithium reagents under mild reaction conditions (0 C), giving almost excellent product yields of up to 95%.

Hydrogen transfer type oxidation of alcohols by rhodium and ruthenium catalyst under microwave irradiation

Secondary alcohols were converted into the corresponding ketones by methyl acrylate and rhodium catalyst efficiently under microwave irradiation. Treatment of primary alcohols with the same condition resulted in the recovery of the starting materials. Primary alcohols were converted into aldehydes by hydrogen transfer reaction using methyl vinyl ketone and ruthenium catalyst under microwave irradiation.