93804-29-6

Basic information

• Product Name: DIMETHYLMETHOXY-N-OCTYLSILANE
• Synonyms: METHOXYDIMETHYLOCTYLSILANE;DIMETHYLMETHOXY-N-OCTYLSILANE;N-OCTYLDIMETHYLMETHOXYSILANE;OCTYLDIMETHYLMETHOXYSILANE;Dimethylmethoxyoctylsilane;dimethyloctylmethoxysilane;Methoxy(dimethyl)octylsilane 98%
• CAS NO: 93804-29-6
• Molecular Formula: C₁₁H₂₆OSi
• Molecular Weight: 202.41
• EINECS: 298-404-7
• Product Categories: Organometallic Reagents;Organosilicon;OthersSelf Assembly&Contact Printing;Self-Assembly Materials;Silanes;Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Others;Self Assembly &Self-Assembly Materials
• Mol File: 93804-29-6.mol
• Article Data: 4

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 221-223 °C(lit.)
• Flash Point: 181 °F
• Appearance: /
• Density: 0.813 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.178mmHg at 25°C
• Refractive Index: n20/D 1.423(lit.)
• BRN: 4362666
• CAS DataBase Reference: DIMETHYLMETHOXY-N-OCTYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYLMETHOXY-N-OCTYLSILANE(93804-29-6)
• EPA Substance Registry System: DIMETHYLMETHOXY-N-OCTYLSILANE(93804-29-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26
• RIDADR: UN 1993 / PGIII
• WGK Germany: 3
• F: 21
• TSCA: No
• Hazardous Substances Data: 93804-29-6(Hazardous Substances Data)

Usage

Uses

Methoxy(dimethyl)octylsilane was used to functionalize partially oxidized porous silicon with silane groups.{89}

InChI:InChI=1/C11H26OSi/c1-5-6-7-8-9-10-11-13(3,4)12-2/h5-11H2,1-4H3

Upstream product

• 111-83-1 1-bromo-octane 
• 3429-76-3 trimethyl-octyl-silane 
• 67-56-1 methanol 
• 226225-89-4 dimethyl(1-octyl)(2-pyridyl)silane 
• 81272-80-2 allyldimethyloctylsilane 

Downstream Products

• 40934-68-7 octyldimethylhydrosilane 
• 111-87-5 octanol 

Relevant articles and documents

Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)-H Borylation at the Methyl Group on Silicon

A conversion of trimethylsilylalkanes into the corresponding alcohols is established based on an iridium-catalyzed, chemoselective C(sp3)-H borylation of the methyl group on silicon. The (borylmethyl)silyl group formed by C(sp3)-H borylation is treated with H2O2/NaOH, and the resulting (hydroxymethyl)silyl group is converted into a hydroxyl group by Brook rearrangement, followed by oxidation of the resulting methoxysilyl group under Tamao conditions. An alternative route proceeding through the formylsilyl group formed from a (hydroxymethyl)silyl group by Swern oxidation is also established. The method is applicable to substituted trimethylsilylcycloalkanes and 1,1-dimethyl-1-silacyclopentane for conversion into the corresponding stereodefined cycloalkyl alcohols and 1,4-butanediol.

Oxidation of 2-Pyridyldimethylsilyl Group to Hydroxyl Group by H2O2/KF. Implication of Fluoride Ion Accelerated 2-Pyridyl-Silyl Bond Cleavage

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