KINETICALLY AND THERMODYNAMICALLY CONTROLLED SYNTHESIS OF 2,6-DISUBSTITUTED CYCLOHEXANONE SEMICARBAZONES. A MOLECULAR MECHANICS STUDY OF A1,3-STRAIN

DOI: 10.1016/S0040-4020(01)91400-0

Source and publish data:

Tetrahedron p. 3791 - 3802 (1985)

Update date:2022-08-03

Topics: Synthesis Semicarbazones Cyclohexanone

Authors:

Castello, Assumpta

Jaime, Carlos

Marquet, Jorge

Moreno-Manas, Marcial

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Article abstract of DOI:10.1016/S0040-4020(01)91400-0

Reasonable values for Me-Me, H-Me and Me-H A^1,3-strain have been evaluated by molecular mechanics calculations on differently substituted methylenecyclohexanes (5.46-6.75, 1.03 and 0.71 kcal/mol, respectively).The chair-to-chair inversion barri

Full text of DOI:10.1016/S0040-4020(01)91400-0

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