Tetrahedron p. 4025 - 4038 (1985)
Update date:2022-08-05
Topics:
Giese, Bernd
Horler, Hans
From aldehydes, ketones and esters β-carbonyl radicals 47 can be generated via enolization, cyclopropanation, solvomercuration and reduction with NaBH4.Radicals 47 react with electron-poor alkenes 27 to give products of CC-bond forming reactions (Tables 1-3).Carbonyl compounds are therefore precursors of three-carbon building blocks.The products result from reactions with "Umpolung".
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