FACILE GENERATION OF DIALKYLAMINYL RADICALS FROM N-HYDROXYPYRIDINE-2-THIONE CARBAMATES. APPLICATION IN KINETIC STUDIES OF SMALL RING CYCLOALKYLAMINYL RADICAL RING OPENINGS

DOI: 10.1016/S0040-4039(01)80910-2

Source and publish data:

Tetrahedron Letters p. 5651 - 5654 (1985)

Update date:2022-08-03

Topics:

Authors:

Newcomb, Martin

Park, Seung-Un

Kaplan, Jere

Marquardt, Donald J.

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Article abstract of DOI:10.1016/S0040-4039(01)80910-2

The preparation of N-hydroxypyridine-2-thione carbamates and the formation of dialkylaminyl radicals from these species are described, and the application of this methodology in kinetic studies of aminyl radical rearrangements is demonstrated.

Full text of DOI:10.1016/S0040-4039(01)80910-2

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