Highly diastereoselective additions of organocopper reagents to 2-exo-bornyl crotonates

DOI: 10.1016/S0040-4020(01)91033-6

Source and publish data:

Tetrahedron p. 9691 - 9702 (1991)

Update date:2022-08-03

Topics:

Authors:

Bergdahl, Mikael

Nilsson, Martin

Olsson, Thomas

Stern, Kaye

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Article abstract of DOI:10.1016/S0040-4020(01)91033-6

Iodotrimethylsilane-activated butylcopper adds to the chiral bornyl crotonates 1-3 in high yields and with good to excellent diastereoselectivities. In the present investigation, these reactions are compared with additions of lithium butylcuprates of vari

Full text of DOI:10.1016/S0040-4020(01)91033-6

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