Heteroatom-Directed Allylic Substitution and Rearrangement Reactions

DOI: 10.1021/jo00381a014

Source and publish data:

Journal of Organic Chemistry p. 782 - 787 (1987)

Update date:2022-08-05

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Authors:

Hagen, James P.

Harris, Joseph J.

Lakin, Danielle

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Article abstract of DOI:10.1021/jo00381a014

Alcoholic, phenolic, and thiolic nucleophiles attack 3-chloro-1-methoxypropene (1) exclusively at C-1 in the presence of N,N-diisopropylethylamine.The reaction is formally a high regioselective S_N2' process.Some of the oxygen nucleophiles (e.g.

Full text of DOI:10.1021/jo00381a014

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