SYNTHESIS OF SOME - AND PROPELLANES WITH SILICON, PHOSPHORUS, SULFUR, TITANIUM, GERMANIUM, OR TIN IN THE LONG BRIDGE

DOI: 10.1016/S0040-4020(01)87604-3

Source and publish data:

Tetrahedron p. 1845 - 1850 (1986)

Update date:2022-09-26

Topics:

Authors:

Butkowskyj-Walkiw, Theodora

Szeimies, Guenter

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Article abstract of DOI:10.1016/S0040-4020(01)87604-3

The doubly lithiated silanes 8b and 13b were cyclized by several dihalides XCl2 affording the <4.1.1>propellanes 9a-g and, respectively, the <3.1.1>propellanes 14a-d.On irradiation of the titanacycle 9f, "titanocene" was eliminated forming the <3.1.1>prop

Full text of DOI:10.1016/S0040-4020(01)87604-3

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