Tetrahedron p. 2873 - 2880 (1986)
Update date:2022-08-04
Topics:
Lipshutz, Bruce H.
Parker, David A.
Nguyen, Sam L.
McCarthy, Keith E.
Barton, John C.
et al.
Novel higher order cuprates, R(2-thienyl)Cu(CN)LiMgBr (2), are prepared from the 1:1:1 combination of CuCN, 2-lithiothiophene and RMgX.Reactions of various members of this new class of reagents are described, including substitution and conjugate addition processes, where the ligand derived from the Grignard reagent is selectively transferred.The effects of added BF3*Et2O are discussed.Some comparison reactions with the corresponding lower order reagents, RCu(CN)MgBr, have also been carried out.Evidence is presented suggesting that species 2, unlike their dilithio analogs, are not discrete.
View MoreHangzhou Yingshanhua Pigment Chemicals Co.,Ltd.
Contact:+86-0150-58101658
Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Nanjing Fayekong Chemcial Co.,Ltd(expird)
Contact:86-25-58813444
Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Zouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
MS( MAOSHENG )Chemical CO.,LTD
Contact:+86-519-82726678.82726378
Address:TAOXI INDUSTRY ZONE JINTAN
Contact:86-15588110016
Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Doi:10.1016/j.tetlet.2008.09.149
(2008)Doi:10.1016/S0040-4039(00)85362-9
(1986)Doi:10.1016/j.tetasy.2008.09.012
(2008)Doi:10.1016/j.mencom.2018.03.029
(2018)Doi:10.1021/jo01073a614
(1960)Doi:10.1080/00397910802324518
(2008)
