CAS No.124-41-4,Sodium methanolate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	124-41-4
Name:	Sodium methanolate
Article Data:	142

Formula:	CH₃NaO
Molecular Weight:	54.024
Synonyms:	Methanol,compounds,sodium salt;Sodium methylate-methanol solution;High pure pharmaceutical solid sodium methoxide;Sodium Methoxide (28% in methanol);Sodium methoxide (liquid and solid);Sodium methoxide-methanol;Sodiummethoxide;solid Sodium Methylate;Sodium methoxide; ( Sodium Methylate);
EINECS:	204-699-5
Density:	0.97 g/mL at 20 °C
Melting Point:	-98 °C
Boiling Point:	48.1 °C at 760 mmHg
Flash Point:	11.1 °C
Solubility:	reacts with water
Appearance:	clear liquid
Hazard Symbols:	F,T,C
Risk Codes:	11-23/24/25-34-39/23/24/25-36/38-14-36/37/38
Safety:	8-16-26-43-45-7-36/37-7/8-36/37/39
Transport Information:	UN 1431 4.2/PG 2
PSA:	23.06000
LogP:	0.04670

Synthetic route

: 67-56-1
methanol

: 51934-08-8
3-Vinylbicyclobutane-1-carbonitrile

A: 124-41-4
sodium methylate

B: 91597-63-6
3-(2-Methoxyethylidene)cyclobutane-1-carbonitrile

C: 91597-62-5
Z-3-vinyl-3-methoxycyclobutane-1-carbonitrile

Conditions

Conditions	Yield
With perchloric acid at 20℃; for 5h; Yields of byproduct given;	A n/a B 35% C n/a

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 107-31-3
Methyl formate

: 68294-03-1
2-(carboxymethyl)-4-methoxybenzoic acid

A: 6-methoxy-1-oxo-1H-isochromene-4-carboxylic acid methyl ester

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
With diethyl ether Erwaermen des danach isolierten Reaktionsprodukts mit konz. wss.Salzsaeure;

...Expand

: 67-56-1
methanol

: 124-41-4
sodium methylate

Conditions

Conditions	Yield
With [Ru4(μ-H)4(CO)12] at 25℃; Rate constant; Equilibrium constant; various carbonyl hydride complexes of Fe, Ru, and Os;
With sodium hydroxide; water at 20℃; Equilibrium constant;
With sodium hydroxide

: 18024-69-6
sodium tetramethoxyborate

A: 121-43-7
Trimethyl borate

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
at 210 - 240℃; im Vakuum;
210-280°C;
210-280°C;
210-280°C;

: 67-56-1
methanol

: 33673-07-3
bis-methoxycarbonyl-methanide

A: 124-41-4
sodium methylate

B: 108-59-8
malonic acid dimethyl ester

Conditions

Conditions	Yield
at 25℃; Equilibrium constant;

...Expand

: 67-56-1
methanol

: 31124-95-5
ethyl cyanoacetate anion

A: 124-41-4
sodium methylate

B: 105-56-6
ethyl 2-cyanoacetate

Conditions

Conditions	Yield
at 25℃; Equilibrium constant;

...Expand

: 67-56-1
methanol

: 48129-94-8
4-nitrobenzyl cyanide anion

A: 124-41-4
sodium methylate

B: 555-21-5
4-Nitrophenylacetonitrile

Conditions

Conditions	Yield
at 25℃; Equilibrium constant;

...Expand

: 67-56-1
methanol

: 64764-41-6
p-cyano-phenyl-acetonitrile anion

A: 876-31-3
4-(cyanomethyl)benzonitrile

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
at 25℃; Equilibrium constant;

...Expand

: 67-56-1
methanol

: 163977-20-6
2-cyanobenzyl cyanide anion

A: 3759-28-2
(2-cyanophenyl)acetonitrile

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
at 25℃; Equilibrium constant;

...Expand

: C15H9N6O13(1-)

A: 19138-90-0
2,2',4.4',6,6'-hexanitrostilbene

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
In methanol; dimethyl sulfoxide at 25℃; Equilibrium constant;

Raw Materials

67-56-1

121-43-7

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Chemistry

Molecular structure of Sodium methanolate (CAS NO.124-41-4) is:

Product Name: Sodium methanolate
CAS Registry Number: 124-41-4
IUPAC Name:&nbsp;sodium methanolate
Molecular Weight: 54.02369 [g/mol]
Molecular Formula: CH₃NaO
H-Bond Donor: 0
H-Bond Acceptor: 1
EINECS: 204-699-5
Melting Point: -98 °C
Flash Point: 11.1 °C
Enthalpy of Vaporization: 35.21 kJ/mol
Boiling Point: 48.1 °C at 760 mmHg
Vapour Pressure: 265 mmHg at 25 °C
Density: 0.97 g/mL at 20°C
Refractive index: 1.3700
Storage temp.: Flammables area
Water Solubility: reacts
Sensitive Moisture: Sensitive
Stability: Stability Highly flammable. Reacts violently with water. Keep container dry. Incompatible with water, acids, chlorinated solvents.
Product Categories: Organics;Classes of Metal Compounds;Na (Sodium) Compounds (excluding simple sodium salts);Typical Metal Compounds

Uses

Sodium methanolate (CAS NO.124-41-4) has very important use in both organic synthesis and industrial applications:
Organic synthesis: It&nbsp;is a routine base in organic chemistry, applicable to the synthesis of numerous compounds, ranging from pharmaceuticals to agrichemicals. As a base, it is employed in dehydrohalogenations and aldol condensations. It is also a nucleophile for the production of methyl ethers.
Industrial applications: It is used as an initiator of an anionic addition polymerization with ethylene oxide, forming a polyether with high molecular weight. Biodiesel is prepared from vegetable oils and animal fats, that is, fatty acid triglycerides, by transesterification with methanol to give fatty acid methyl esters (FAMEs). This transformation is catalyzed by sodium methoxide.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	2037mg/kg (2037mg/kg)	SENSE ORGANS AND SPECIAL SENSES: CHROMODACYRORREA: EYE BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: DYSPNEA	National Technical Information Service. Vol. OTS0555267,

Safety Profile

Statements: 11-23/24/25-34-39/23/24/25-36/38-14-36/37/38
R11:Highly flammable.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R34:Causes burns.
R39:Danger of very serious irreversible effects.
R36/38:Irritating to eyes and skin.
R14 :Reacts violently with water.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 8-16-26-43-45-7-36/37-7/8-36/37/39
S8:Keep container dry.
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.&nbsp;<br /> S36/37:Wear suitable protective clothing and gloves.
S7/8:Keep container tightly closed and dry.&nbsp;<br /> S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1431 4.2/PG 2
WGK Germany: 1
RTECS: PC3570000
F: 9-21
TSCA: Yes
HazardClass: 4.2
PackingGroup: II
HS Code: 29051900

Specification

Sodium methanolate , its cas register number is 124-41-4. It also can be called Sodium methoxide ; Sodium methylate .It is a colorless cloudy white liquid consisting of sodium methylate, a solid, dissolved in methyl alcohol.It is&nbsp;highly flammable and reacts with water to produce a mixed solution of sodium hydroxide and methyl alcohol.