Chemistry Letters p. 137 - 140 (1987)
Update date:2022-09-26
Topics:
Uyehara, Tadao
Kawai, Yoshinori
Yamada, Jun-ichi
Kato, Tadahiro
Pinacol-type rearrangement of 1-methoxybicyclo<3.2.2>nona-3,6-dien-2-ols proceeds preferentially to give bicyclo<3.2.2>nona-6,8-dien-2-ones by treating with TsOH in boiling benzene.This transformation is incorporable in a new synthesis of homobarrelenone
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