Chemistry of the 2,5-didehydropyridine biradical: Computational, kinetic, and trapping studies toward drug design

DOI: 10.1021/ja9730223

Source and publish data:

Journal of the American Chemical Society p. 376 - 385 (1998)

Update date:2022-09-26

Topics:

Authors:

Hoffner, Johannes

Schottelius, Marc J.

Feichtinger, Derek

Chen, Peter

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Article abstract of DOI:10.1021/ja9730223

A combined computation, kinetic, and trapping study of the 2,5-didehydropyridine biradical finds the hydrogen abstraction reaction to be unable by protonation. The observation of small amounts of pyridine products in the thermolysis of a C,N-dialkynylimin

Full text of DOI:10.1021/ja9730223

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