Ring contraction of 1,2,4,5,7,8-hexaoxa-3-silonanes by selective reduction of COOSi fragments. Synthesis of new silicon-containing rings, 1,3,5,6-tetraoxa-2-silepanes

DOI: 10.1021/jo8023957

Source and publish data:

Journal of Organic Chemistry p. 1917 - 1922 (2009)

Update date:2022-07-31

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Authors:

Terent'ev, Alexander O.

Platonov, Maxim M.

Tursina, Anna I.

Chernyshev, Vladimir V.

Nikishin, Gennady I.

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Article abstract of DOI:10.1021/jo8023957

The reducing agents Ph3P, (C₈H₁₇)₃P, or NH₂C(S)NH₂ promote the ring contraction of nine-membered triperoxides, viz., 1,2,4,5,7,8-hexaoxa-3-silonanes, giving rise to seven-membered rings belonging to t

Full text of DOI:10.1021/jo8023957

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