A Novel Method for Furan Annelation by the Regioselective Acylation of Allylic Sulfides via α-Silyl Intermediates

DOI: 10.1055/s-1987-28081

Source and publish data:

Synthesis p. 811 - 814 (1987)

Update date:2022-09-26

Topics:

Authors:

Hiroi, Kunio

Sato, Hiroyasu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1987-28081

Aluminum chloride-catalyzed acylations of allylic phenyl sulfides 3 with acid chlorides 5 were carried out via α-silyl intermediates 4 to give γ-acylated vinylic sulfides 6 with complete regioselectivity.Treatment of the γ-acylated compounds with concentr

Full text of DOI:10.1055/s-1987-28081

Products guided by the article

Product name:1-Pentanone, 1-[2-[(phenylthio)methylene]cycloheptyl]-

Cas No:113967-14-9

R&D Labs maybe for 113967-14-9

Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
QINGDAO DEVELOP chemistry Co.,Limited

Contact:+86-532-85807910

Address:98#Nanjing Road, Qingdao, China 266071
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China

Relevant to this article

Immobilization and chiral recognition of 3,5-dimethylphenylcarbamates of cellulose and amylose bearing 4-(trimethoxysilyl)phenylcarbamate groups

Doi:10.1002/chir.20722
(2010)
Chiral Synthesis via Organoboranes. 18. Selective Reductions. 43. Diisopinocampheylchloroborane as an Excellent Chiral Reducing Reagent for the Synthesis of Halo Alcohols of High Enantiomeric Purity. A Highly Enantioselective Synthesis of Both Optical Isomers of Tomoxetine, Fluoxetine, a

Doi:10.1021/jo00248a005
(1988)
Synthesis of 6- or 8-bromo flavonoids by regioselective mono-bromination and deprotection protocol from flavonoid alkyl ethers

Doi:10.1002/bkcs.10286
(2015)
N-(4-(4-(2,3-dichloro- or 2-methoxyphenyl)piperazin-1-yl)butyl) heterobiarylcarboxamides with functionalized linking chains as high affinity and enantioselective D3 receptor antagonists

Doi:10.1021/jm900095y
(2009)
Doi:10.1021/jo01102a603
(1958)
Anti-selective epoxidation of methyl α-methylene-β-tert- butyldimethylsilyloxycarboxylate esters. evidence for stereospecific oxygen atom transfer in a nucleophilic epoxidation Process

Doi:10.1021/ol900665a
(2009)

Article Doi