A Novel Method for Furan Annelation by the Regioselective Acylation of Allylic Sulfides via α-Silyl Intermediates

DOI: 10.1055/s-1987-28081

Source and publish data:

Synthesis p. 811 - 814 (1987)

Update date:2022-09-26

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Authors:

Hiroi, Kunio

Sato, Hiroyasu

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Article abstract of DOI:10.1055/s-1987-28081

Aluminum chloride-catalyzed acylations of allylic phenyl sulfides 3 with acid chlorides 5 were carried out via α-silyl intermediates 4 to give γ-acylated vinylic sulfides 6 with complete regioselectivity.Treatment of the γ-acylated compounds with concentr

Full text of DOI:10.1055/s-1987-28081

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