DABCO CATALYZED COUPLING OF α-KETO ESTERS WITH ACRYLONITRILE AND METHYL ACRYLATE

DOI: 10.1016/S0040-4039(00)96506-7

Source and publish data:

Tetrahedron Letters p. 4351 - 4352 (1987)

Update date:2022-08-02

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Authors:

Basavaiah, D.

Bharathi, T. K.

Gowriswari, V. V. L.

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Article abstract of DOI:10.1016/S0040-4039(00)96506-7

Coupling of acrylonitrile to α-keto esters is readily achieved using 1,4-diazabicyclo(2.2.2)-octane(DABCO) as a catalyst to produce 2-(1-carboalkoxy-1-hydroxyalkyl)acrylonitriles in good yields.Similar reaction with methyl acrylate produces the corresponding 2-substituted acrylates.

Full text of DOI:10.1016/S0040-4039(00)96506-7

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