DABCO CATALYZED COUPLING OF α-KETO ESTERS WITH ACRYLONITRILE AND METHYL ACRYLATE

DOI: 10.1016/S0040-4039(00)96506-7

Source and publish data:

Tetrahedron Letters p. 4351 - 4352 (1987)

Update date:2022-08-02

Topics:

Authors:

Basavaiah, D.

Bharathi, T. K.

Gowriswari, V. V. L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96506-7

Coupling of acrylonitrile to α-keto esters is readily achieved using 1,4-diazabicyclo(2.2.2)-octane(DABCO) as a catalyst to produce 2-(1-carboalkoxy-1-hydroxyalkyl)acrylonitriles in good yields.Similar reaction with methyl acrylate produces the corresponding 2-substituted acrylates.

Full text of DOI:10.1016/S0040-4039(00)96506-7

Products guided by the article

Product name:Butanedioic acid, hydroxymethylene(4-methylphenyl)-, 1-ethyl 4-methyl ester

Cas No:114070-30-3

R&D Labs maybe for 114070-30-3

Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China

Relevant to this article

UEBER ANTIMON-HALTIGE HETEROCYCLEN VII. 2-PHENYL-1,3-DITHIA-2-STIBOLAN,<*>HELICAL-VERKNUEPFTE FUENFRING-EINHEITEN

Doi:10.1016/S0022-328X(00)98894-6
(1987)
Palladium(II)-catalyzed asymmetric coupling of allylic alcohols and vinyl ethers: Insight into the palladium and copper bimetallic catalyst

Doi:10.1021/jo802807w
(2009)
Cyclometalation of 2,2 -bipyridine. mono- and dinuclear C,N platinum(II) derivatives

Doi:10.1021/om801033g
(2009)
2,4-Bis(4-methylphenylthio)-1,3,2λ⁵,4λ⁵-dithiadiphosphetane-2,4-dithione: A New Reagent for Thiation of N,N-Disubstituted Amides

Doi:10.1002/hlca.19870700412
(1987)
Synthesis of triphenylamine-based thiophene-(N-aryl)pyrrole-thiophene dyes for dye-sensitized solar cell applications

Doi:10.1016/j.tet.2012.04.104
(2012)
Synthesis, reactivity and characterization of mono-, bi- and tri-nuclear Schiff-base palladacycles with aromatic N-heterocycles

Doi:10.1016/j.jorganchem.2012.04.026
(2012)

Article Doi