Total Synthesis of Dictymal, a B-seco-Dictymenoid Aldehyde from an Alga, Dictyota dichotoma

DOI: 10.1246/cl.1987.2295

Source and publish data:

Chemistry Letters p. 2295 - 2298 (1987)

Update date:2022-08-05

Topics:

Authors:

Kato, Nobuo

Tanaka, Shinya

Kataoka, Hideo

Takeshita, Hitoshi

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Article abstract of DOI:10.1246/cl.1987.2295

A B-seco-dictymenoid aldehyde, dictymal, was synthesized from two optically active iridoid synthons; the required ring system was constructed by lactol-regulated Cope rearrangement and stereoselective Li-tert-BuOH-in-HMPA reduction of the tetrasubstituted

Full text of DOI:10.1246/cl.1987.2295

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