Chemistry Letters p. 2295 - 2298 (1987)
Update date:2022-08-05
Topics:
Kato, Nobuo
Tanaka, Shinya
Kataoka, Hideo
Takeshita, Hitoshi
A B-seco-dictymenoid aldehyde, dictymal, was synthesized from two optically active iridoid synthons; the required ring system was constructed by lactol-regulated Cope rearrangement and stereoselective Li-tert-BuOH-in-HMPA reduction of the tetrasubstituted
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