Dehydrogenation of LGeH by a lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C6F5) 3 and trimethylsilyl diazomethane: An unprecedented rearrangement of a diazocompound to an is

DOI: 10.1021/ic900341r

Source and publish data:

Inorganic Chemistry p. 7645 - 7649 (2009)

Update date:2022-09-26

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Authors:

Jana, Anukul

Objartel, Ina

Roesky, Herbert W.

Stalke, Dietmar

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Article abstract of DOI:10.1021/ic900341r

Herein we report the dehydrogenation of LGeH (1) [L = CH{(CMe)(2,6-/Pr ₂C₆H₃N)}₂] by a frustrated Lewis NHC borane pair under the formation of an imidazolium borate salt (2) and the heterocyclic germylene L'Ge (

Full text of DOI:10.1021/ic900341r

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