Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 335 - 342 (1985)
Update date:2022-08-04
Topics:
Lelievre, Joel
Gaboriaud, Rene
The rates and formation and dissociation of the thermoaddition complex of 1,3,5-trinitrobenzene with OH- has been investigated in micellar solutions of dodecyltrimethylammonium bromide (DTABr) using a stopped-flow spectrometer.We have observed and measured three processes which proceed under different conditions of acidity: (a) formation of the ? complex, (b) spontaneous (equilibrium) dissociation in less basic solutions and (c) dissociation via proton attack in acid solutions.These processes are influenced by the background KBr electrolyte.The interphase potentialΔφ =φm-φw, depicted in the pseudophase model, allows us to explain the variations of the rate constants.
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