Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 335 - 342 (1985)
Update date:2022-08-04
Topics:
Lelievre, Joel
Gaboriaud, Rene
The rates and formation and dissociation of the thermoaddition complex of 1,3,5-trinitrobenzene with OH- has been investigated in micellar solutions of dodecyltrimethylammonium bromide (DTABr) using a stopped-flow spectrometer.We have observed and measured three processes which proceed under different conditions of acidity: (a) formation of the ? complex, (b) spontaneous (equilibrium) dissociation in less basic solutions and (c) dissociation via proton attack in acid solutions.These processes are influenced by the background KBr electrolyte.The interphase potentialΔφ =φm-φw, depicted in the pseudophase model, allows us to explain the variations of the rate constants.
View MoreSichuan Mianzhu Ronghong Chemical Co.,LTd
Contact:8613981840544
Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
Contact:86-371-63655023
Address:No.85,jinshui road,zhengzhou,China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd
Contact:+86-533-5415882
Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Shaanxi King Stone Enterprise Company Limited
Contact:86-29-88353805,13609285751
Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
Contact:+86-025-52406782
Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
Doi:10.1055/s-2002-33511
(2002)Doi:10.1002/chem.200700228
(2007)Doi:10.1016/j.bmcl.2011.03.099
(2011)Doi:10.1016/S0040-4039(02)01062-6
(2002)Doi:10.1016/S0040-4039(02)01626-X
(2002)Doi:10.1021/ol026588r
(2002)
