Fine regioselective tuning in the oxidation of sec,sec 1,2-diols by dimethyldioxirane

DOI: 10.1016/0040-4020(96)00615-1

Source and publish data:

Tetrahedron p. 10969 - 10978 (1996)

Update date:2022-08-04

Topics:

Authors:

Bovicelli, Paolo

Sanetti, Anna

Lupattelli, Paolo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00615-1

Non-symmetric sec,sec 1,2-diols and their o-isopropylidene derivatives undergo a regioselective oxidation by dimethyldioxirane depending on the electronic effects of the substituents. These results support previous views about the concerted O-insertion mechanism via a polar transition state.

Full text of DOI:10.1016/0040-4020(96)00615-1

Products guided by the article

Product name:2-hydroxy-1-<(4-nitro)-phenyl>-1-propanone

Cas No:1205-57-8

R&D Labs maybe for 1205-57-8

Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China

Relevant to this article

5-Lipoxygenase-activating protein inhibitors. Part 2: 3-{5-((S)-1-Acetyl-2,3-dihydro-1H-indol-2-ylmethoxy)-3-tert-butylsulfanyl-1-[4-(5-methoxy-pyrimidin-2-yl)-benzyl]-1H-indol-2-yl}-2,2-dimethyl-propionic acid (AM679)-A potent FLAP inhibitor

Doi:10.1016/j.bmcl.2009.10.131
(2010)
Chelation control in the [3+3] annulation reaction of alkoxy-substituted 1,1-diacylcyclopropanes with 1,3-bis(trimethylsilyloxy)-1,3-butadienes. Diversity-oriented synthesis of isochromanes

Doi:10.1021/jo902334q
(2010)
Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of a-lithiated epoxides

Doi:10.1021/jo9022974
(2010)
Cycloaddition of nitrones with arynes generated from benzobisoxadisilole or 2,3-naphthoxadisilole

Doi:10.1016/j.tet.2009.11.097
(2010)
Porous coordination polymer with flexibility imparted by coordinatively changeable lithium ions on the pore surface

Doi:10.1021/ic902077j
(2010)
Isonitriles from the Baylis-Hillman adducts of acrylates: viable precursor to tetrazolo-fused diazepinones via post-Ugi cyclization

Doi:10.1016/j.tetlet.2009.11.051
(2010)

Article Doi