Tetrahedron p. 10969 - 10978 (1996)
Update date:2022-08-04
Topics:
Bovicelli, Paolo
Sanetti, Anna
Lupattelli, Paolo
Non-symmetric sec,sec 1,2-diols and their o-isopropylidene derivatives undergo a regioselective oxidation by dimethyldioxirane depending on the electronic effects of the substituents. These results support previous views about the concerted O-insertion mechanism via a polar transition state.
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