NIckel(0)-Promoted Cyclization of 1,n-Diynes with Isocyanide: The First Practical Synthesis of Polycyclic Iminocyclopentadienes

DOI: 10.1021/jo00276a004

Source and publish data:

Journal of Organic Chemistry p. 3517 - 3519 (1989)

Update date:2022-08-05

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Authors:

Tamao, Kohei

Kobayashi, Kenji

Ito, Yoshihiko

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Article abstract of DOI:10.1021/jo00276a004

1,n-Diynes having alkyl, aryl, and trimethylsilyl groups as the terminal substituents undergo cyclization with 2,6-dimethylphenyl isocyanide in the presence of a stoichiometric amount of bis( cyclooctadiene)nickel(0) to form polycyclic iminocyclopentadien

Full text of DOI:10.1021/jo00276a004

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