Dicarbonylnitrosyl(cyclohexadienyl)rhenium cations: Synthesis, electrochemistry, and nucleophilic addition reactions

DOI: 10.1021/om00113a019

Source and publish data:

Organometallics p. 2631 - 2637 (1989)

Update date:2022-08-03

Topics:

Authors:

Pike, Robert D.

Alavosus, Timothy J.

Camaioni-Neto, Catherine A.

Williams Jr., John C.

Sweigart

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Article abstract of DOI:10.1021/om00113a019

Grignard reagent addition to [(arene)Re(CO)₃]PF₆ (1b) gives the corresponding (cyclohexadienyl)Re(CO)₃ complexes (2b). When the dienyl carbons in 2b all bear methyl substituents, treatment with NOPF₆ affords the

Full text of DOI:10.1021/om00113a019

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Product name:{((C₆H₆)(C₆H₅))Re(CO)3}

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