Journal of the American Chemical Society p. 10018 - 10020 (2010)
Update date:2022-09-26
Topics:
Ghadwal, Rajendra S.
Roesky, Herbert W.
Granitzka, Markus
Stalke, Dietmar
Reaction of IPr·SiCl2 (1) [IPr) 1,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic CdN bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
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(2010)
