Tetrahedron p. 4503 - 4516 (1990)
Update date:2022-08-04
Topics:
Takle, Andrew
Kocienski, Philip
Key steps in the first total synthesis of Lacrimin A (2) include (a) the use of methoxyallene as an enone-1,3-dianion equivalent; (b) the use of a new copper-catalysed migratory insertion reaction to construct a tri-substituted alkene stereoselectively; and (c) the use of a Pd(0)-catalysed coupling reaction to generate an isochromanone ring.
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(2011)
