ASYMMETRIC ALKYLATIONS OF A SULTAM-DERIVED GLYCINATE EQUIVALENT: PRACTICAL PREPARATION OF ENANTIOMERICALLY PURE α-AMINO ACIDS

DOI: 10.1016/S0040-4039(01)93840-7

Source and publish data:

Tetrahedron Letters p. 6009 - 6010 (1989)

Update date:2022-08-05

Topics:

Authors:

Oppolzer, Wolfgang

Moretti, Robert

Thomi, Silvia

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Article abstract of DOI:10.1016/S0040-4039(01)93840-7

Deprotonation/alkylation of sultam-derived N-glycinate equivalent 3 gave crystalline products 5 which on mild hydrolysis furnished α-amino acids 7 (ca.100percent e.e.) in high overall yield.

Full text of DOI:10.1016/S0040-4039(01)93840-7

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