Relative Rates for the Addition Reactions of the Malonyl Radical to Substituted Styrenes Induced by Cerium(IV) Ammonium Nitrate and Tributyltin Hydride. A Comparison

DOI: 10.1021/jo00309a010

Source and publish data:

Journal of Organic Chemistry p. 5688 - 5691 (1990)

Update date:2022-08-04

Topics:

Authors:

Baciocchi, Enrico

Giese, Bernd

Farshchi, Hassan

Ruzziconi, Renzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00309a010

The relative rates for the addition reactions of the malonyl radical to substituted styrenes induced by cerium(IV) ammonium nitrate (CAN) and tributyltin hydride have been determined.The two processes exhibit practically identical ρ⁺ values (-1.05 and -1.06), thus suggesting that the coordination between the metal and the radical does not play a significant role in the CAN-promoted oxidative additions.

Full text of DOI:10.1021/jo00309a010

Products guided by the article

Product name:2-[2-(3-Chloro-phenyl)-2-methoxy-ethyl]-malonic acid dimethyl ester

Cas No:128752-84-1

R&D Labs maybe for 128752-84-1

Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com

Relevant to this article

SYNTHESIS OF VINCA ALKALOIDS AND RELATED COMPOUNDS XLVIII SYNTHESIS OF (+)-CATHARANTHINE AND (+/-)-ALLOCATHARANTHINE

Doi:10.1016/S0040-4020(01)81977-3
(1990)
Growth, optical, luminescence, thermal and mechanical behavior of an organic single crystal: 3-Acetyl-2-methyl-4-phenylquinolin-1-ium chloride

Doi:10.1016/j.saa.2013.12.041
(2014)
Reactions of oxidobis(quinolin-8-olato)vanadium(IV) with hydroxamate ligands: A route providing mixed ligand and Quinolin-8-olato-Free Vanadium(IV) Complexes

Doi:10.1246/bcsj.20120066
(2012)
Synthesis of 2′,3′-modified carbocyclic L -nucleoside analogues

Doi:10.1002/ejoc.201001473
(2011)
2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

Doi:10.1039/c0nj00787k
(2011)
A direct one-step preparation of triarylverdazylium salts from the corresponding triarylformazans

Doi:10.1055/s-1997-1516
(1997)

Article Doi