Bulletin of the Chemical Society of Japan p. 2118 - 2121 (1991)
Update date:2022-07-30
Topics:
Chida, Noritaka
Ohtsuka, Masami
Ogura, Katsuyuki
Ogawa, Seiichiro
Conversion of hex-5-enopyranosides into substituted cyclohexenones (Ferrier rearrangement) was found to proceed efficiently with a catalytic amount of various mercury(II) salts at room temperature in a neutral solvent system.Among the mercury(II) salts tested, mercury(II) trifluoroacetate showed the highest activity.Four optically active cyclohexenones were prepared from hex-5-enopyranosides utilizing this method.
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