Organic and Biomolecular Chemistry p. 5104 - 5108 (2011)
Update date:2022-08-02
Topics:
Coote, Susannah C.
Quenum, Seidjolo
Procter, David J.
A tag removal-cyclisation sequence is described that is initiated by reduction using a Sm(ii) species and completed by a Sm(iii) Lewis acid that is formed in an earlier stage. Therefore, the reaction cascade utilises both oxidation states of a samarium reagent in discrete steps and allows access to privileged, pyrrolidinyl-spirooxindole scaffolds and analogues inspired by the anti-cancer natural product spirotryprostatin A. The Royal Society of Chemistry 2011.
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Doi:10.1016/j.tetlet.2011.06.024
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