Chemistry Letters p. 2085 - 2088 (1990)
Update date:2022-08-02
Topics:
Tachibana, Junichi
Imamura, Taira
New dioxygen molybdenum porphyrins were formed by the introduction of dioxygen into the toluene solutions of oxomolybdenum(IV) porphyrins, MoIVO(tpp) and MoIVO(oep), around -70 deg C.By raising the temperature to 25 deg C, or by the photoirradiation of the solutions with the wavelength of the Soret bands, the parent oxomolybdenum(IV) porphyrins were regenerated.A structure for the dioxygen complexes is proposed.
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Doi:10.1021/jo200958a
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