SYNTHESIS OF STATINE FROM (S)-MALIC ACID; STEREOCONTROL VIA RADICAL CYCLIZATION

DOI: 10.1016/S0040-4039(00)92639-X

Source and publish data:

Tetrahedron Letters p. 401 - 404 (1991)

Update date:2022-08-03

Topics:

Authors:

Koot, Wim-Jan

Ginkel, Roel van

Kranenburg, Mirko

Hiemstra, Henk

Louwrier, Saskia

et al. et al.

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Article abstract of DOI:10.1016/S0040-4039(00)92639-X

Highly stereoselective syntheses of enantiomerically pure γ-amino acids statine and 4-epi-statine from (S)-malic acid are described by using, respectively, an intramolecular α-acylamino radical reaction and an intermolecular N-acyliminium allylsilane coupling.

Full text of DOI:10.1016/S0040-4039(00)92639-X

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