Kinetic resolution of planar-chiral (η6-arene)chromium complexes by molybdenum-catalyzed asymmetric ring-closing metathesis

DOI: 10.1002/anie.201108292

Source and publish data:

Angewandte Chemie - International Edition p. 2951 - 2955 (2012)

Update date:2022-08-04

Topics:

Authors:

Ogasawara, Masamichi

Wu, Wei-Yi

Arae, Sachie

Watanabe, Susumu

Morita, Tomotaka

Takahashi, Tamotsu

Kamikawa, Ken

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Article abstract of DOI:10.1002/anie.201108292

Molybdenum-catalyzed asymmetric ring-closing metathesis has been used for the kinetic resolution of racemic planar-chiral (η⁶-arene) chromium complexes with excellent enantioselectivity. The products are excellent precursors for the synthesis of various planar-chiral (η⁶-arene) chromium derivatives and can also be applied as chiral ligands in rhodium-catalyzed asymmetric reactions. Copyright

Full text of DOI:10.1002/anie.201108292

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