Tetrahedron Letters p. 5227 - 5230 (1993)
Update date:2022-08-04
Topics: Synthesis Chiral Enantioselective Catalysis Monosubstituted Oxiranes
Corey, E. J.
Helal, Christopher J.
A new catalytic enentioselective synthesis of monosubstituted oxiranes has been developed from achiral trichloromethyl ketones by (a) enentioselective carbonyl reduction, (b) selective bis-dechlorination and (c) base-induced ring closure of the resulting chlorohydrins.
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