Palladium-catalyzed Reaction of Isoprene with Water in Presence of Carbon Dioxide and Base

DOI: 10.1246/bcsj.56.637

Source and publish data:

Bulletin of the Chemical Society of Japan p. 637 - 638 (1983)

Update date:2022-08-04

Topics:

Authors:

Inoue, Yoshio

Sato, Michio

Satake, Masaki

Hashimoto, Harukichi

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Article abstract of DOI:10.1246/bcsj.56.637

Palladium(0)-catalyzed reaction of isoprene with water was enhanced by the presence of carbon dioxide and a base to give dimethyloctadienols.The same catalyst was found to dehydrate the dimethyloctadienols to afford the corresponding dimethyloctatrienes.The effect of acidity of water on the isoprene-water reaction was also studied.

Full text of DOI:10.1246/bcsj.56.637

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