Influence of strain on chemical reactivity. Relative reactivity of torsionally strained double bonds in 1,3-dipolar cycloadditions

DOI: 10.1021/ja00038a059

Source and publish data:

Journal of the American Chemical Society p. 4846 - 4855 (1992)

Update date:2022-09-26

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Authors:

Shea, Kenneth J.

Kim, Jang-Seob

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Article abstract of DOI:10.1021/ja00038a059

The addition of picryl azide to a series of mono- and bicyclic olefins including trans- cycloalkenes and bridgehead alkenes is reported. Secondary reaction products were identified, and their mechanism of formation was explained by an analysis relating th

Full text of DOI:10.1021/ja00038a059

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