Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. 3. Nitriles: Synthesis of Pyridine and Pyrimidine Derivatives

DOI: 10.1021/jo00048a043

Source and publish data:

Journal of Organic Chemistry p. 6020 - 6025 (1992)

Update date:2022-08-05

Topics:

Authors:

Bartoli, Giuseppe

Bosco, Marcella

Cimarelli, Cristina

Dalpozzo, Renato

De Munno, Giovanni

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00048a043

A new method for the construction of pyridine and pyrimidine derivatives is described, based on the electrophilic attack of nitriles to dianions of β-(monoalkylamino)-α,β-unsaturated ketones and the subsequent cyclization of the addition product.The react

Full text of DOI:10.1021/jo00048a043

Products guided by the article

Product name:2-(4-bromophenyl)-N-isopropyl-6-phenyl-4-pyridinamine

Cas No:143889-50-3

R&D Labs maybe for 143889-50-3

Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County

Relevant to this article

Interconversion of nitrenes, carbenes, and nitrile ylides by ring expansion, ring opening, ring contraction, and ring closure: 3-Quinolylnitrene, 2-quinoxalylcarbene, and 3-quinolylcarbene

Doi:10.1071/CH08523
(2009)
REACTION OF AROMATIC DIAZO DERIVATIVES WITH GLYCINE AND GLYCINE METHYLAMIDE

Doi:10.1007/BF00765002
(1990)
Doi:10.1016/S0040-4039(00)71572-3
(1967)
Characterization of an epoxide hydrolase from the Florida red tide dinoflagellate, Karenia brevis

Doi:10.1016/j.phytochem.2015.11.002
(2016)
Enantio- and diastereoconvergent cyclocondensation reactions: Synthesis of enantiopure cis-decahydroquinolines

Doi:10.1002/chem.201302894
(2013)
Four discrete transition metal complexes involving pyridyl-substituted nitronyl nitroxide: Syntheses, crystal structures, and magnetic properties

Doi:10.1002/zaac.201300266
(2014)

Article Doi