Journal of the Chemical Society. Chemical communications p. 1102 - 1103 (1992)
Update date:2022-08-04
Topics:
Masuyama, Yoshiro
Hayakawa, Akiko
Kurusu, Yasuhiko
Heterogeneous carbonyl allylation by γ-substituted allylic alcohols with Pd-SnCl2 in nonpolar solvent such as diethyl ether was promoted by ultrasound to cause α-addition, with a regioselectivity which is the inverse of that in homogeneous carbonyl allylation in polar solvents such as dimethylformamide, 1,3-dimethylimidazolidin-2-one and tetrahydrofuran-H2O.
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